Job Landscape in Arizona Arizona offers a wide variety in its economical landscape. Three of the top sectors, however, include government, transportation and healthcare. The five C's of copper, citrus, cattle, cotton and climate have a large influence on Arizona jobs. In fact, Arizona provides about two thirds of the nation's copper production. Arizona's unemployment rate, as of September 2014, stood at 6.9 percent according to the Bureau of Labor Statistics. That's a percentage point above the national average. However, there is still a broad base of jobs in Arizona. Walmart is the biggest private sector job source, while state government is Arizona's largest employer overall. In addition to Walmart, other major corporate employers are Banner Health, Wells Fargo, Bank of America and McDonald's. Some of the biggest cities include Phoenix, Mesa, Glendale, Peoria and Tempe. Looking for jobs in Arizona is a lot easier with the help of the tools and resources at LiveCareer. It's a good idea to check out the extensive database of resume samples for help writing a standout resume of your own. No matter what level of employment you seek or in which industry, a professional and well-written resume is needed to get you in the door.